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Thermo Scientific Chemicals
2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF
CAS: 193065-68-8 | C5H10BrO2Zn- | 247.417 g/mol
| Catalog Number | Quantity |
|---|---|
| H26739.AD | 50 mL |
Chemical Identifiers
CAS193065-68-8
IUPAC Namezinc(2+) 3-ethoxy-3-oxopropan-1-ide bromide
Molecular FormulaC5H9BrO2Zn
InChI KeyAPPDFGHVJHZDKS-UHFFFAOYSA-M
SMILES[Zn++].[Br-].CCOC(=O)C[CH2-]
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Specifications
Specification Sheet
Specification SheetCommentMay form a precipitate on storage
Refractive Index1.4220-1.4300 @20?C
Complexometric Titration0.40M - 0.60M
Appearance (Color)Brown to dark brown
FormLiquid
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, be
In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, be
RUO – Research Use Only
General References:
- Knochel, P,; Singer, R. D. Preparation and Reactions of Polyfunctional Organozinc Reagents in Organic Synthesis. Chem. Rev. 1993, 93 2117-2188 .
- Kim, S.-H.; Rieke, R. D. Recent Advance in Heterocyclic Organozinc and Organomanganese Compounds; Direct Synthetic Routes and Application in Organic Synthesis.Molecules. 2010, 15 8006-8038..