亚磷酸三苯基酯, 97%
亚磷酸三苯基酯, 97%
亚磷酸三苯基酯, 97%
Thermo Scientific Chemicals

亚磷酸三苯基酯, 97%

CAS: 101-02-0 | C18H15O3P | 310.289 g/mol
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货号数量
A18662.36
又称 A18662-36
500 g
货号 A18662.36
又称 A18662-36
价格(CNY)
-
数量:
500 g
请求批量或定制报价
化学标识符
CAS101-02-0
IUPAC Nametriphenyl phosphite
Molecular FormulaC18H15O3P
InChI KeyHVLLSGMXQDNUAL-UHFFFAOYSA-N
SMILESO(P(OC1=CC=CC=C1)OC1=CC=CC=C1)C1=CC=CC=C1
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规格Specification Sheet规格表
Appearance (Color)Clear colorless to pale yellow
FormLiquid
Assay (GC)≥96.0%
Refractive Index1.5885-1.5935 @ 20?C
Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions. Also used as reagent in the preparation of mixed valent nickel diphosphine dithiolate bridged iron carbonyl phosphine complexes as models of [NiFe]-hydrogenase active site.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions. Also used as reagent in the preparation of mixed valent nickel diphosphine dithiolate bridged iron carbonyl phosphine complexes as models of [NiFe]-hydrogenase active site.

Solubility
Insoluble in water.

Notes
Air and Moisture Sensitive, store away form air and moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas.
RUO – Research Use Only

General References:

  1. John D Meeker; and Heather M Stapleton. House dust concentrations of organophosphate flame retardants in relation to hormone levels and semen quality parameters. Environmental Health Perspectives, 2010, 118 (3), 318-323.
  2. Ken-ichiro Murata; and Hajime Tanaka. Surface-wetting effects on the liquid-liquid transition of a single-component molecular liquid. Nature Communications, 2010, 116.