2-(乙氧基羰基)乙基锌化溴,0.5M THF溶液
2-(乙氧基羰基)乙基锌化溴,0.5M THF溶液
2-(乙氧基羰基)乙基锌化溴,0.5M THF溶液
2-(乙氧基羰基)乙基锌化溴,0.5M THF溶液
Thermo Scientific Chemicals

2-(乙氧基羰基)乙基锌化溴,0.5M THF溶液

CAS: 193065-68-8 | C5H10BrO2Zn- | 247.417 g/mol
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货号数量
H26739.AD50 mL
货号 H26739.AD
价格(CNY)
-
数量:
50 mL
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化学标识符
CAS193065-68-8
IUPAC Namezinc(2+) 3-ethoxy-3-oxopropan-1-ide bromide
Molecular FormulaC5H9BrO2Zn
InChI KeyAPPDFGHVJHZDKS-UHFFFAOYSA-M
SMILES[Zn++].[Br-].CCOC(=O)C[CH2-]
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规格Specification Sheet规格表
CommentMay form a precipitate on storage
Refractive Index1.4220-1.4300 @20?C
Complexometric Titration0.40M - 0.60M
Appearance (Color)Brown to dark brown
FormLiquid
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, be
RUO – Research Use Only

General References:

  1. Knochel, P,; Singer, R. D. “Preparation and Reactions of Polyfunctional Organozinc Reagents in Organic Synthesis. Chem. Rev. 1993, 93 2117-2188 .
  2. Kim, S.-H.; Rieke, R. D. “Recent Advance in Heterocyclic Organozinc and Organomanganese Compounds; Direct Synthetic Routes and Application in Organic Synthesis”.Molecules. 2010, 15 8006-8038..